A Comprehensive Guide to Gypsum Products in Dentistry

Explore the different types of gypsum products, their properties, and applications in modern dentistry.

Gypsum powder and dental tools on a white background

What Are Gypsum Products?

Gypsum products are a cornerstone of dental laboratory work, essential for creating accurate models and casts from which dental prostheses and appliances are constructed. Derived from a naturally occurring mineral, gypsum is processed to create various types of dental plaster and stone. The choice of a specific gypsum product depends on the required precision, strength, and handling characteristics for a particular clinical application. Understanding the properties and correct manipulation of these materials is fundamental to achieving successful restorative and prosthetic outcomes in dentistry. This guide provides a comprehensive overview of the different types of gypsum products used in modern dentistry.

Gypsum Products Summary (Types I-V)

Type I: Impression Plaster +
Name: Impression Plaster
Chemical Name: β-hemihydrate
W/P Ratio: 0.50-0.75 ml/g
Working Time: 3-5 min
Initial Setting Time: 2-4 min
Final Setting Time: 5-10 min
Strength: 6-15 MPa
Set Expansion: 0.00-0.15%

Advantages

Fast setting time and low cost.

Disadvantages

Brittle and inelastic, making it unsuitable for many applications.

Application

Primarily used for impressions, though now considered obsolete in many practices.

Type II: Model Plaster +
Name: Model Plaster
Chemical Name: β-hemihydrate
W/P Ratio: 0.45-0.50 ml/g
Working Time: 3-4 min
Initial Setting Time: 5-12 min
Final Setting Time: 15-30 min
Strength: 15-25 MPa
Set Expansion: 0.00-0.30%

Advantages

Economical and features easy trimming.

Disadvantages

Exhibits lower strength and higher porosity compared to other types.

Application

Commonly used for study models and articulator mounting.

Type III: Dental Stone +
Name: Dental Stone
Chemical Name: α-hemihydrate
W/P Ratio: 0.28-0.30 ml/g
Working Time: 3-4 min
Initial Setting Time: 8-15 min
Final Setting Time: 30-40 min
Strength: 40-60 MPa
Set Expansion: 0.00-0.20%

Advantages

Good strength and balanced properties for a variety of uses.

Disadvantages

More expensive than model plaster and has a longer setting time.

Application

Ideal for working models and constructing dentures.

Type IV: Die Stone (High-Strength/Low-Expansion) +
Name: Die Stone (HS-LE)
Chemical Name: Modified α-hemihydrate
W/P Ratio: 0.22-0.24 ml/g
Working Time: 3-5 min
Initial Setting Time: 12-20 min
Final Setting Time: 45-60 min
Strength: 60-90 MPa
Set Expansion: 0.00-0.10%

Advantages

Maximum accuracy and high strength for precision work.

Disadvantages

More expensive and requires skill to manipulate correctly.

Application

Used for crown and bridge dies and implant models where precision is critical.

Type V: Die Stone (High-Strength/High-Expansion) +
Name: Die Stone (HS-HE)
Chemical Name: Modified α-hemihydrate
W/P Ratio: 0.18-0.22 ml/g
Working Time: 3-4 min
Initial Setting Time: 12-18 min
Final Setting Time: 30-45 min
Strength: 70-100+ MPa
Set Expansion: 0.10-0.30%

Advantages

Highest strength and a controlled, higher expansion to compensate for metal shrinkage.

Disadvantages

The most expensive option and involves complex manipulation.

Application

Primarily for base-metal cast investment where high strength and expansion are needed.

Quick Reference Summaries

Essential Chemical Information +
AspectDetailsExamination Points
Natural GypsumCaSO₄·2H₂O (calcium sulfate dihydrate)White/yellowish mineral, worldwide
Setting ReactionCaSO₄·½H₂O + 1.5H₂O → CaSO₄·2H₂O + HeatExothermic: 3900 cal/g mol
Temperature Rise8-10°C above ambientPeak at 12-15 minutes
Solubility RatioHemihydrate:Dihydrate = 4:1 at 20°CDrives dissolution-precipitation
Setting TheoryDissolution-precipitation (accepted)6 stages: Mix→Dissolve→Supersaturate→Nucleate→Grow→Set
ADA Classification Quick Reference +
TypeNameChemical FormW/P RatioStrength (MPa)Key Use
IImpression Plasterβ-hemihydrate0.50-0.754-8Obsolete
IIModel Plasterβ-hemihydrate0.45-0.509+Study models
IIIDental Stoneα-hemihydrate0.28-0.3020.7+Working models
IVDie Stone (HS-LE)Modified α0.22-0.2434.5+Crown/bridge dies
VDie Stone (HS-HE)Modified α0.18-0.2248.3+Casting dies
Clinical Selection Guide +
Clinical NeedPrimary RequirementRecommended TypeRationale
Study ModelsEconomyType IICost-effective, adequate strength
Case PresentationAppearanceType IIClean, white finish
Complete DenturesProcessing strengthType IIIHeat resistance, stability
Partial DenturesHandling durabilityType IIIModerate strength
Crown/Bridge DiesPrecision + strengthType IVLow expansion, high strength
Implant ModelsMaximum accuracyType IVDimensional stability
Base Metal CastingExpansion compensationType VControlled high expansion

High-Yield Examination Facts

Must-Know Chemical Equations & Critical Numbers +
Calcination: CaSO₄·2H₂O + Heat → CaSO₄·½H₂O + 1.5H₂O
Setting: CaSO₄·½H₂O + 1.5H₂O → CaSO₄·2H₂O + Heat (3900 cal/g mol)
Solubility Ratio: 4:1 (hemihydrate:dihydrate at 20°C)
Storage Humidity: <70% RH maximum
Temperature Rise: 8-10°C during setting
Wet to Dry Strength: 2-3× improvement

Troubleshooting

Problem-Solution Matrix +
ProblemMost Likely CauseQuick SolutionPrevention
Fast SettingHigh temperature, contaminationCool water, clean equipmentTemperature control
Slow SettingExcess water, retardersCheck W/P ratio, fresh powderAccurate measurement
Weak CastToo much waterReduce W/P ratioDigital scale use
Air BubblesPoor techniqueImprove mixing/pouringVibration, surfactants
Poor SurfaceContaminationClean impressionProper preparation

Manipulation Protocol Checklist

View the Protocol +

Pre-Mixing Phase

  • Fresh powder (<6 months old)
  • Accurate digital scale (±0.1g)
  • Graduated cylinder for water
  • Clean, dry mixing equipment
  • Room temperature (20-25°C)

Mixing Phase

  • Water added first to bowl
  • Powder sifted gradually into water
  • 30-second wetting period
  • 60-second controlled spatulation
  • Gentle vibration to remove air

Pouring Phase

  • Impression cleaned and treated
  • Continuous mechanical vibration
  • Sequential pouring (corner to corner)
  • Complete filling verification

Setting Phase

  • Undisturbed environment maintained
  • Minimum setting times observed
  • Temperature rise monitored
  • Safe separation timing
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